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If it doesn't work you could try linking it to a bank transfer that supported on Steam, if paypal is an option at checkout on Steam, link your Vanilla prepaid master card to paypal, then use paypal on Steam. Otherwise do what 8bitbread said above, buy a physical steam gift card. You could call the vanilla prepaid mastercard company, and ask if they were blocking Steam, if they are tell them to unblock Steam.
Now you could use your Vanilla prepaid mastercard to buy things from 3rd party retailers that selling game keys for Steam, can use tool site like isthereanydeal.com this tool site help you find best deals on games across other stores, and 3rd party retailers for Steam keys.