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make sure your not mixing up 1 for I (i), 0 for O, 8 and B, etc
For as old as Stalker is, there were bunches of games you could buy on Steam, or buy a physical copy. And whether that key on the physical copy could be used on Steam wasn't guaranteed. And there's certainly a thousand cases of old games that either pre-date Steam or had side-by-side versions where Steam doesn't support every CD key ever generated for the game.
Heck you can't even put in old Half-Life keys from pre-Steam days anymore.
https://www.gog.com/reclaim
Note the Original STALKER game had a cdkey that was ONLY for MP. Bascially it wasnt a steam key. so the key wont work on steam anyway
As others have noted you can use it to get a GOG copy
Every once a while a publisher has uploaded his old keys to Steam -- but if your key is shown as invalid, they clearly didn't do that for those.