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But usually you dont need a CD key to reinstall your old games on a new PC as long as you are logged into the same Steam account as always.
Because no one can help you without basic information like the name of the game.
Anyway, has nothing to do with Steam, as Games for Windows LIVE is a Microsoft service. Contact their support if you have an issue with their game.
Did the OP try right-clicking on library game title?
I found it, thanks to all who helped