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https://support.steampowered.com/kb_article.php?ref=7710-tdlc-0426
Steam (top left) > settings > downloads > Steam Library Folders > add library folder
I recommend you put Steam on C and then install games on whatever drive you feel like using the library folders like snapjack said. You can even move all the games using Steam to the other folder without reinstalling.
You can also just create the library folder, exit steam and move the steamapps folder to the new drives folder and restart Steam and it should all detect the games.
This way you can try games on whatever drive you want, you can even default to put it on D but then you can move specific games back if you get problems.