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I'm assuming he bought it physical and then tried to activate the Steam key on his (newly created) Steam account? I don't see where an email comes in there.
or he mean something other
Ukrainian payment system does not work, as everywhere else, there is the purchase of steam wallet card codes, and getting via email - perhaps talking about this?
return it to retail market, and buy in Steam
when key activated once, CD key tied to account forewer
There's no way to redeem a key if he wasn't logged in to an account, so the account was at least created (or he was logged into another one). At this point it sounds like an account recovery issue. Try to see how far you get with the options in support for that and else create a ticket to recover the account.