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I think you just helped me figured out the issue. She wasn't accepting my potion either, and realizing the reward with your comment, I noticed my potion slots were full for Thunderbrew, one of the rewards.
I drank one and talked to her again and was able to receive the reward, which, sure enough included another Thunderbrew.
I was simply maxed out before.
I did save and re-load as well just in case, so do that too if drinking a potion to make space doesn't fix it right away.
TL;DR: SOLVED - Make sure your potion/tool wheel isn't full for each potion slot, being at capacity prevents receiving her reward if you already have the max (12 by default) of the potions she gives you back.