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Great Permutator is a pretty good one:
http://www.youtube.com/watch?v=7FzCZJUEe5w
And the "obvious" answer would be The Codex of Alchemical Engineering, which is more or less the predecessor of Spacechem. Meaning also it is not nearly as polished or good, but still worth a look:
http://www.zachtronics.com/the-codex-of-alchemical-engineering/
http://steamcommunity.com/sharedfiles/filedetails/?id=141005475
It's only $2.09 on Desura right now so I bought it. Looks pretty engaging.
http://store.steampowered.com/app/235980/
It not that challenging but very nice ... and sometimes you have to use your brain as well.
It on sale this week, I really recommend it!
http://store.steampowered.com/app/266010/
Looks neat.
Another puzzles that are NOT like spacechem at all, but very enjoyable, are:
Braid,
The Swapper (currently on flash sale, GET IT!),
Antichamber,
Vessel (I loved it and the music!),
Closure (another not very known game, but EXCELLENT with a very nice mechanic), and
The Bridge, (amazing! And it felt really good to beat it without having to look for guides)
As for non steam, I loved nintendo Picross and any other nonogram game.
Puzzles are definitely among my favorite game genres!
I find the great permutator more difficult than spacechem. The great permutator is a "find the unique solution" type of game, very different from spacechem.
If you want something like spacechem, there is this web game "runestone wisp" : http://runestonewisp.appspot.com/ , it is very good but not very good looking