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"It's REEAAAALLY powerful! Especially against living things!"
In short: good against non-zombie enemies.
https://steamcommunity.com/sharedfiles/filedetails/?id=1638708067
They're basically shotgun shells, in Claire's scenario, but usually just for removing zombies from the equation by headshotting them with one so their arms, torso and head melts off and kills them.
However it's typically better just to make SMG ammo instead, for the final bosses. Need that DPS. You find more than enough flame rounds on the side, too.
they deal alot more damage to birkin, Mr.x and lickers while doing less damage to zombies and ivy. I have been playing on hardcore and acid rounds are lifeblood, they down Mr.x faster (who also walks faster on hardcore) 2-3 shots lickers (it takes 3-5 flame rounds to kill them on hardcore) and it stunts birkin in all his forms, also it leaves a DoT on everything it hits so sometimes you can hit Mr.X twice and the DoT will put him down, also on a few runs I killed g3 and 4 while running away because of the DoT.
the only thing you should use your white gun powder for is acid rounds.
Considering the shotgun can 1 shot zombies most of the time, making certain areas a breeze, I'm often surprised why people prefer Claire. Even with bosses, the normal weapons, hell, even the knife, are faster.