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Doesn't really matter when you open because when they drop they all ready have a pre set item inside. You can't save scum them basically.
if you mean transmarvel sigils you can actually save scum those if you run a quest inbetween. otherwise you get the same results again if you don't run a quest in between.
Very low chance from curios only as already stated. Just RNG. Open your curios whenever you feel like it. No method to improve your odds. Just go with your gut.