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Issue was that my hardware was incompatible with the shipped libeay32.dll version, so for future reference if anyone else with newer hardware encounters similar issues.
Download a newer version of "libeay32.dll" and replace it in the substance main directory and it should launch like a charm.
https://substance3d.adobe.com/documentation/spdoc/crash-or-freeze-during-startup-182266673.html
Thanks Memo, it worked for me!