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You can check if what you are looking for is featured there possibly, but I have not noticed any statements about "Vertex colors/alpha".
Previous releases of niftools are instead more obligated to work on Blender 2.5.x which can still be set up, though requires a bit of effort.
I cannot speak for exporting in Blender 2.79 as I personally felt after trying many different versions that nothing really worked in the NIF-category.
I have had success ONLY re-sculpting (consistent vert counts, etc.) so far, and exporting in 2.80 with the latest pre-release despite a few setbacks, having to use NifSkope to fill in any blanks within the exported .nif file itself.
Beyond the aforementioned versions I would instead recommend consulting other 3D software such as 3DSMax if you are looking to work with NIF files to a higher degree.
You are not likely to have a great experience with 2.79 currently as far as as NIF is concerned, unless there is an edition that I have missed somewhere else that works well with exports.