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Not true, once you know an enchantment effect you can use it on any item which can be enchanted with that effect.
Unfortunately, OP, I can't think of anything that will help, have you tried it with different shields in your inventory (in case there's one specific shield which has bugged out)? I'm guessing you've got an un-enchanted shield in your inventory (obv can't put an enchantment on an already enchanted item - just mentioning that on the off chance you didn't realise it, though it sounds like you're probably past that point) and when you select a soul gem and the Resist Magic effect the shield(s) just isn't showing up as an option to enchant? What type of shield are you using, and does it allow you to place other enchantments on the shield, just not RM?
(Just trying to be thorough in case someone else comes along and knows a fix.)
My morning for being ninja'd! Nice going gnewna! And good morning!
The Shield of Solutide from "The wolf Queen Awakened" can be disenchanted for a "better" version of Resist magic, which at lv100 enchanting yields 25% instead of 20% and can stack with normal resist magic for a total of 45% magic resistance.
Normal magic resistance is probably easiest to find as an enchanted piece of jewelry either store-sold or as random loot in dungeons at middling + levels.