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https://skyrim.gamepedia.com/Spell_Tome:_Ash_Shell
Another of my old characters with Ash Shell has 61 alteration, so skill level seems to be the problem.
That you have seen the Firebolt (not Fireball) spell tome for the first time is surprising, as the leveled list shows Chance None = 0, Use All is set and the starting level is 1, so you should see this spell tome at all times.
BTW, best wiki to use is the UESP Wiki[en.uesp.net].