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Apocrypha usually has black soul gems lying around.
Also, Blackreach has geode deposits you can mine for soul gems, though their payout is also random. You might get all Petty, you might get Grand, you might get black or you might not.
Anywhere you find mages, you can find soul gems. Necros almost always have black gems.
I think OP means filled gems
On the college front, Enthir is a smuggler of magical artifacts so he also has his reasons for carrying this form of magical contraband.
Soul Cairn is not deep in Dawnguard. You can get there way before level 10.