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Use this for details, and maybe to find other mobs that drop the item you need:
http://steamcommunity.com/sharedfiles/filedetails/?id=1242812444
Maybe he has the best drop chances, but in my experience, Act 5 heroes are pretty rare. If his spawn rates are very low, it will not matter much.
If I were you, I would go try to trade for it. I know there is not a lot of people on for trading nowdays, put it could be much easier. And faster.
If you are not into trading, wich is fine, you can still do regular boss runs. When I'm looking for any purples I do Hydra > Manticore > Aktaios > Dragon Liche > Fafnir > Dvergr Lords > Fungoid King (as they have decent drops and are relatively close to a fountain/portal.) Depending on your active fountain, you can do Thrym, Hades, Surtr, Talos, etc. My personnal favorite is Thrym.
Last boss at the very end of act 5. Hopefully the door isn't bugged for you. I'm stuck inside Land's End.
He's at the final area (Muspelheim). You need to go right a whole lot from waypoint then you need to clear through a large fort with a blocked door. The door is unblocked by getting an item from a boss to the west. Enter fort, defeat Loki, then clear fort. Once fort is clear there is a narrow lane you follow to the boss fight.