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I mean, you can transform 500C steam into water, but for me it feels like beating a nail with microscope. 30k km of travel from Vulcanus to Nauvis and back will give you giant amount of ice even with basic asteroid tech. 2 Platforms with 2-3k ice brick is more than enough to supply your Vulcanus needs.
But sure, local steam transformation is more convenient. ) You may use it as is.
Absurd. Acid neutralization from a single chem plant produces 2000 steam per second from the nearly infinite stores of sulfuric acid and calcite, which in turn can supply two chem plants condensing it to water at 180/s between the two. Ice melting does it at a comparatively meager 20/s. Don't waste your platform's time dropping ice to Vulcanus.
And you'd still need chemical plants to melt the ice anyway.
The amount of water you can get out of steam is insane.
You're missing out on figuring out the Vulcanus specific processes.
For someone who has just arrived on Vulcanus for the first time it is not immediately obvious that the supply of calcite is 'nearly infinite'. (Acid, yes.)