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Unfortunately I can't tell you where you get the recipe as I never had to go out of my way to unlock them so I have to assume there's something that has to be crafted by hand that you might have missed. The grimoire is also needed to make the nucleus helm and pocket dimension, so you could try making digital gold, the jotunhelm, or the teleporter pad just in case one of those somehow got wrapped up in the unlock requirements despite not being necessary for the null grenade.
Edit: Also, the witches don't drop the grimoire, so I'm not really sure what you've got there. Probably the censers.
Hey thanks for the help, I managed to make a couple of null grenades, but unsure how to use them. I threw one at the field and nothing happened.