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Afaik there are no missable ultimate weapons or limit breaks.
There are missable materias, weapons and armor (i believe there are stealable armor from enemies in the desert prison, and from enemies once you go to the underwater reactor you can miss out). there are other missable things, being the leviathan scales, if you don't grab them after you fight the robot with arms on disc two. You can miss a materia and a weapon if you don't grab it. I think there's another weapon you can miss there but I don't remember.
Some summons are missable, like the one on the boat and bahamut zero if you fail to obtain all four large materias.
The first enemy skill materia you obtain is missable.
There are two enemy skills that are missable forever, one being trine (you get it from a boss behind niblehiem, and from enemies in the desert), and the other being Pandora's box, which you can only get from the very first bone dragon enemy that you fight. If you fail to obtain it, you can't get it again (i think due to a bug in the code).
That's all i can remember, you can do more research if you're worried about a specific item or whatever being missable.
I guess it's aptly named, lol.
It's definitely true for Barret's weapon. If the OP doesn't mind spoilers, here's a FAQ about missables:
https://gamefaqs.gamespot.com/ps/197341-final-fantasy-vii/faqs/27656