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Devestator can be either bought from weapon dealer in fancy flats in Act2 or found for free is Act3 in police station.
What I would suggest is buying ammo only in the Act2, and getting shotgun for free in Act3 and then getting more ammo from weapon merchant.
Then use it until you spend all its ammo and throw it away.
If anybody knows any other location for its ammo, please let me know.