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That Ascendancy Shrine is only for respeccing I believe once you have done your third qualification trial (75+ for your 6 points total, but not sure since I have never done it maybe you return back? Should be a video on it somewhere lol).
Chaos trial is a bit tricky and is not really straightforward unlike Sekhema.
Anyways you have to collect the three different unique Fate tablets from the Three normal random Trial bosses. Once you have all three, you use them at the end (?) of the trial to open the door to the Trialmaster's Tower. Then you have to fight the Trial Master to get the last Ascendancy points.
Edit:
https://www.poe2wiki.net/wiki/The_Trial_of_Chaos
Also:
https://www.youtube.com/watch?time_continue=4&v=e1BGi4017MA&embeds_referring_euri=https%3A%2F%2Fwww.bing.com%2F&embeds_referring_origin=https%3A%2F%2Fwww.bing.com&source_ve_path=Mjg2NjY
Should help. Based on the video the biggest problem is that you can't do it all in one run cause the tablets only drop for bosses that are the 10th. So you probably need to farm them or buy them first before doing proper level Trial run to combat Trialmaster.