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https://bindingofisaacrebirth.gamepedia.com/Devil_Room
https://bindingofisaacrebirth.gamepedia.com/Angel_Room
Consider downloading it if you're confused. It can make it easier to understand by visually showing you the exact percentages of the chances for these rooms to spawn.
If you have the Afterbirth+ DLC, then this mod is already added to the base game, and you can turn it on in the options.
Well for what I can recall about your question (trying to make it a bit simple):
To get devil deals, on the second floor of the first chapter do not get hit and defeat the boss while you have 100% on the devil deal (try getting soul hearts from tinted rocks or try to be careful) and pick the item that is on the floor of the Devil Room (which costs hearts and you might want to look for info in http://platinumgod.co.uk/ so you know what you are taking). This will cause angel rooms to never spawn and have a percentage each time you are in a floor to get an X% of probability on getting a devil deal (Unless you unlock Duality).
For Angel room you need to do the same as if you would do a Devil deal, however, you must go into the room after defeating the boss, do not take any active or passive item and then leave the room. At this point, when you drop into the next chapter first floor you will see there is a value on the angel rooms; it will represent the X% of probability of getting an Angel room as well as Devil room (it is a separated X%).
There are items or actions that affect the % of the rooms appearing:
+Devil Rooms:
-Pentagram
-Black Candle
-Book of Revelations
-Destroying a Beggar
-Goat Head
-Joker Card
-Teleport 2.0
+Angel Rooms:
-Rosary
-Donating 10 coins on donation machine
-Holding the Key Pieces 1 or 2 (both as well are good)
-Killing Devil Beggars, Key Master or Shell Game Beggar
-Donating to a Normal Beggar until it pays out.
-If you get "You feel blessed! fortune in sacrificie room
-Eucharist
-Joker Card
-Teleport 2.0
Hope I could help