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And where is your Steam directory at? Mine's at C:\Steam\steamapps\common\Command and Conquer 3 Tiberium Wars and it runs normally, using Windows 7 64-bit, no compatibility mode or 'run as admin'.
Another thought: Have you tried verifying your install? (Right click the game in your library->Properties->Local Files->Verify)
If that does not do the trick, uninstalling, wiping all remaining files (back up saves) from both the install directory and your Documents\Command & Conquer 3 Tiberium Wars directory, and reinstalling, might be a last resort.