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Impact Glass - Forms as molten sand cools after a meterite impact in the desert. The glass you mention the Egyptians using is from a meteroite impact 26 million years ago in what is now Libya.
Trinitite (USA)/Kharitonchik (Russia) - Glass (often green) formed from sand (or some other silica rich material) after an atmospheric nuclear detonation.
Fulgurite - Glass formed from sand struck by lighting. Tends to be spidery, almost like tree roots.
Given the size of the glass shards in Kenshi as well as what little we do know about the history of the planet, I don't think it's unreasonable to assume the glass formed as a result of the use of nuclear, or similarly energetic weapons (i.e. orbital bombardment via mass drivers), some time during/after the "War of Behemoths" and fall of the First Empire.
http://kenshi.wikia.com/wiki/History_of_Kenshi
https://en.wikipedia.org/wiki/Trinitite
Damn! Darth coming in hot with the facts.
Having said that I wished there was a use for them in game:-(
I mean, look at it that way, if our civilization was to be extinct tomorrow, in a thousand year the most common artifacts would be glass bottles. Plastic last decades/centuries at most, metal rust, wood rot, building crumble to dust, but glass last thousands of years.
Look at the Roman and Greek, the most common relic, by a large margin, are pottery remnant. To the point they hold no archelogical value anymore, and they can be trashed without remorse. With the exception of high quality/unique ones.
Well, the chunks are a bit large to be from a beer bottle. It would be funny to discover that the behemoths used really huge bottles...