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Both programs have their strength, neither is a better program.
I prefer OpenCanvas most of the time, as the image editing tools are very helpful.
OpenCanvas has the social network http://www.portalgraphics.net/pg/ that allows in many cases to download the artwork you like and play it back in Open Canvas so you can see how it was made and try to duplicate the art and techniques.
Black Ink has the freedom to create any brush you can wish for. That's the strength of Black Ink, and the reason to purchase it. The UI is smoother in Black Ink than it is in OpenCanvas. These two things are what is better in Black Ink than Open Canvas.
In virtually any and all areas I have not mentioned, Open Canvas is unquestionably stronger for the user.
My Paint
http://mypaint.intilinux.com/
Alchemy
http://al.chemy.org/gallery/
thats free too
https://inkscape.org/en/
the last time I used black ink, I couldn't figure out how to make brushes that blend similar to SAI, and apparently a blending engine is not high on the priority list for implementation so it can't exactly make any brush you could wish for.
Gwinda and 5ifty7even are right. There's plenty of OpenSource digital art options out there. krita and alchemy are really nice. MyPaint just kinda makes me long for the perfect GUI of ArtRage. You might consider looking to MangaLabo - http://www.portalgraphics.net/en/cl/ . It's rebranded now, but it's still got a no fluff interface from it's professional yesterdays. It used to be one of a few software in Japan that was used for commercial comic creation. If you're looking to do single page or multiple page illustration, using what professionals used to use to pay their rent isn't a bad way to go.