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https://forums.warframe.com/forum/149-bug-reports/
Well, the toxin proc itself doesn't need to be the killing blow, Toxin just needs to be present in the damage calculation of the hit that kills the enemy. The Arquebex does have native Heat damage on the explosions - which is where the real damage is - so you just need to put in some elemental combo that involves Heat before the Toxin mod to ensure the Toxin is alone; having a string of Electrified Barrel+Combustion Rounds+Venomous Clip for example should do it.
You probably put the elements in wrong order so the Toxin combined with Heat into Gas damage.
Which knowing your track record is an unsurprising mistake.
It works for me.
It doesn't work for you.
Ergo YOU did something wrong.
I have no faith in you not doing something wrong because you have LONG history of making threads not understanding the most basic mechanics of this game. Go fix your mods.