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http://www.uesp.net/wiki/Oblivion:Controls
I think you must have messed up something in Oblivion.ini. It is the only possible way you might be able to assign escape keybinding to do something else then open Option.
Go to My Games/Oblivion folder on your user account and move it out to keep a copy, or delete it. Restart game and Oblivion will make a new Oblivion.ini with default settings.
If don't know where Oblivion.ini is, then use Windows Search on your system and it should find it.
TAB is the default keybinding to open journal with F1 to F4 for direct access to each section.
You can use Console in Oblivion to save your game.
http://www.uesp.net/wiki/Oblivion:Console_Command_Tutorial