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For soul gems you have to grab the grand variety. It's found on any guild, as well.
Then you have to find a mage to enchant the item for you. Or do it yourself. But find a mage. The chance to fail with one is pretty much nil.
Here are merchants that offer spells with Restore Health effect and their location: https://en.uesp.net/wiki/Morrowind:Restoration_Spells#Restore_Health
As for constant effect enchantment: only a few souls allow for constant effect enchantment and they all require a Grand Soul Gem, the highest tier soulgem, or Azura's Star. The soul in the gem also has to be above 400 value. The easiest way to get a minimum 400 soul is to summon a Golden Saint (from scrolls or a spell) and soultrap that.
Here's otherwise a list of souls and their soultrapping values: https://en.uesp.net/wiki/Morrowind:Souls
And here's a list of where you can find a Grand Soul Gem (besides as random loot in more difficult dungeons): http://en.uesp.net/wiki/Morrowind:Soul_Gems#Grand_Soul_Gem
If you've never enchanted before, you should know that the Enchanting skill in Morrowind is very finicky. Even with a high level Enchanting skill, enchanting something yourself will very often fail (there are probably ways to get around that with massive fortify intelligence boosts, but I've never really done that so I couldn't tell you). A foolproof way to enchant items is to go to an enchanter (e.g. Galbedir in the top floor of Balmora's Mages Guild) and let them enchant an item for you, but it's VERY expensive for Constant Effect enchantments. (I would guess like over 10,000 gold expensive for the Constant restore health 5pts enchantment you want).
Another thing to keep in mind is the enchanting value of clothing, or basically how suitable it is to be enchanted. The better the quality of the clothing item, the better enchantments you can put on it. For constant effect enchantment, I think it's guaranteed you need the highest tier of clothing (for a ring, it's the Exquisite Ring that is worth 240 gold)
Here's a list of clothing items and their enchantment value:
https://en.uesp.net/wiki/Morrowind:Base_Clothing
You can experiment with it ingame, you will notice that lower level clothing won't allow you some enchantments, especially Constant Effect, like there's a limit on how high you can enchant an item.
Sorry I can't explain to you how it works exactly because I've been playing with the Morrowind Rebirth mod which completely rebalances the enchanting system, but with this basic info I think you can experiment in game and see how it goes.