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I don't know what you want to do, but the games should just work.
https://www.protondb.com/app/38450
https://www.protondb.com/app/613240
Install mint, install steam using the apt command, enjoy the games.
Older Steam games works BETTER under Linux than they do under Windows,,,
Backing them up… I'm unsure but as long as DRM can be dealt with, I'm guessing you could move the files to your drives and then use dosbox to play them? You could always look up guides and from an internet search and try it, though you may face issues as a new user. Then again there's the option to buy the digital version as you mentioned.
Getting them to work might be possible. If you did it on windows, my suggestion is to use the same steps, and try to find repository/open source alternatives to the software you used in the process back then. If those exist you'll probably be able to get it to work in the same way. Then you can either use dosbox or one of its forks or use retroarch or even the windows one with proton if you have to.
Though I want to confirm, you did get it working on windows successfully right? Because you mentioned that you tried.