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Not sure if throwing love potions at them often enough until they drop a fertilized egg would work either but I haven't seen any information on it.
the Charisma requirement is still needed through.
as fore Love Potion's/Aphrodisiac well they do exist, but if they catch you in trying to Drug them they will not like it, so you will have to mix it whit something i guess.
but usually just gifting them something in the category they like is often easier depending on the Rarity of course.
You need to get them to 75 affinity, and for unique NPCs like the shrine maidens or adventurers, you also need to challenge them and defeat them, then you have the charisma check after that. These NPCs tend to be no joke, the Mifu shrine maiden can blast ice arrows out for like 300 damage or something.
From what I have seen, you can get the buff once, then the dialog option goes away forever. I asked for a blessing from the NPC in Mifu village, then returned many times over the course of a year to try to recruit her through normal dialog and the blessing option never came back.
For Unique NPC you need +75 relationship and challenge+defeat them in battle to recruit
The +75 is an easy condition. From my experience, I got 75 Negotiation skill so i can raise every NPC to around +55 relationship just by talking 2-3 days. the rest can be with gift or "love potion" blend into food. Each love potion give around +20 to +25. Love potions are randomly sale by witch shop in Mysilia.
The Hard part is defeat Unique NPC in combat. If you are not strong enough then i suggest recruit Mirage B (Non-Unique NPC can be recruit with just +75 score) from Mech town that sold gun.
Also they have different Charisma score requirement at the end which can easily by pass with equipment.