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1) Radio Island
2) Rubber Duck Island
3) Green Isle
These are not all the places, they just have high concentrations of it.
https://steamcommunity.com/sharedfiles/filedetails/?id=3157397015
Sulphur boulders are bright yellow. They can be found in abundance on the ocean bottom near the volcano. When you approach a harvestable ore boulder, the pickaxe icon will appear. Do yourself a favor and craft or invest in an ore detector, although once you learn the typical locations you won't need it - just revisit the same spots whenever they respawn.
Edit: There is also a good bit of copper and iron at Clifton Outpost, but be prepared to fight for it.
After first wood wall jump up the rocks/mountain on right side.
There you will find a lot iron and cooper - ready to mine...