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Sulphur is kinda rare.
I think someone else had posted the just farmed the Bound that drop gunpowder. Most likely using a perpetual night realm card and choosing a realm that has the bomb throwing bound.
Can also fail the "Simon Says" shrines on purpose to spawn them.
So now you have two threads instead of just looking it up in your guidebook? Really?
So far I've only been forest, and I find caves on the sides of cliffs, often at the edge of water of some kind. Usually there are one or more of bears, spiders and then sulfur, coal and (in the Abeyance/Artisan levels) Shining ore and amber.
The Fae Portal also leads to mini vaults which have a lot of barrels with coal in them too.
You say you have not found such caves, but yet you went on to mention fae portals which I have only seen in caves.
Caves are easy to find on most realm maps you only nee dot look for two things. The fae portal and a clump of POIs all close together.