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There's a slag->sour water trade that's useful for getting additional sulfur and ammonia, and then when you inevitably have too much sulfur as a result, there's a sulfur-> sludge trade that will give you fuel gas and compost when digested. The fuel gas can be burned for power, or processed into diesel or naphtha, and the compost goes towards fertilizer.
Indeed... trading it never crossed my mind. In 1000+ hours, I've never actually traded slag or sour water.
Most people probably don't truly need to; however, as you get later into the game, you have to start locking down your shore line so you can build more docks (or just for aesthetic reasons). At some point you run out of (convenient) ocean to dump in. Depending on what you're doing, you may have multiple belts worth of slag you need to get rid of.
You can use slag (via a crusher) and add it to production for concrete
See image for use
https://steamcommunity.com/sharedfiles/filedetails/?id=3151100084
Haven't the Developers increased the limits of the maps so running out of ocean is less of an issue? Also, it seems to me the oceans are a bit shallower than they used to be.
I also always set the height value in the custom settings to max. Maybe that setting only applies to the land heights and not the ocean depths?