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Orbital collectors need 30 MW
Taking the gas giant in my starter system as an example it has 0.8877377/s Hydrogen and 0.03772246/s Deuterium
Orbital collectors have a base speed of x8 so that's approximately 7.1/s and 0.3/s
Resources are burned according to power density and collection rate, hydrogen and deuterium both have 9MJ so only collection rate is considered.
This particular gas giant has a 96/4 split so 96% of the power needed comes from the hydrogen and 4% from the deuterium
Or 28.8MW and 1.2MW respectively.
This translates to 3.2 hydrogen/s and 0.13 deuterium/s
So final extraction rates are 3.9 hydrogen/s and 0.17 deuterium/s
If your vessels are set to 100% load minimum they won't go until there is 200/400/whatever your current vessel size is. Assuming a size of 200 it will take around 19.5 minutes for a collector to accrue enough deuterium.
I would recommend either doing the full 40 collectors which'll get you 8000 per 20 minutes in the above example (6.6/s) or using the hydrogen and fractionators to generate deuterium.
Fractionators are limited by belt speed so assuming you have mark 2 belts that's 12 per second, they have a 1% chance to convert hydrogen into deuterium so I'd expect around 1 per 8 seconds or 1 per second per 8 fractionators.
Veins Utilisation can drastically impact the rates however as the amount burned for power is flat and does not change.
At VU 2 the collection rate on Orbital Collectors is 11.2x which bumps up the rates in the above example to 9.94/s and 0.42/s which after power drain are 6.74/s and 0.29/s so almost doubling both rates. It'd take 11.5 minutes for a collector to accrue 200 deuterium which with 40 collectors would be 11.6/s vs 6.6/s with no VU.
Oh also there is a checkbox to say whether vessels are allowed to collect from orbital collectors or not, make sure it says they can. To be fair I probably should have led with that XD
check box in the bottom right of the ILS window iirc