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No, there are certain ways to despele enemy spells. (bann-bomb of an achlemist, and last not least despel magic and greater despel magic) And you just need access to the spellbook. What you're talking about is "dismiss magic" not "dispel" You can dismis your own magic effects anytime, as long as you're alive. Even in mid-combat. Most of the time, it's a level 0-spell. But for a kineticist, for example, it's an ability. (hence, in the abiltiy-roster.) So there's no need to go to the inventory.
I didn't try out dominate, yet, But I think the enemies just turn to allies, AI-Controlled, if you do that. So - at least without mods - there's not way to dissmiss-magic for enemy-spell-effects.
But most demons and enemies are immune to mind-effects anyway.