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I had the perk that gives you 15% more rare items. Didn't seem to add backpacks to regular vendors.
EDIT: You can shwack the Steel Shield Mercs @ Mikhaylich Tavern to get 1 backpack, but you have to deal with them during the start of each faction questline either way, so this one's difficult to miss.
Another one drops during the final confrontation @ Mutant Underground, if you shwack the Red Guards. Dunno if any of the Muties drops one if you decide to go with Red Guard.
Otherwise, if you wanna purchase your packs, the only merch who sells proper backpacks (ERMACs) more or less regularly , is the gunsmith @ 7th Heaven...
Apart from that, they are a rare sight in all shops that sometimes have armor in stock, but I'll guess that you'd have better luck finding a pack at a vendor that regularly sells armor, unlike the faction vendors or blackmarket, who only rarely sell a piece. The Smith @ Police HQ is probably your best bet.