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The best heavy armor i found was 20 AC from vendor 21 from a boss (house of hope?)
For medium armor AC16 to buy and a unique AC15 medium armor in Last Light Inn which adds total dex bonus on top (AC15+5 dex = 20 AC) which is also nice.
For heavy armor you can choose between maybe 10% less chance to get hit for crit immunity and for medium armor the unique armor but the problem is you would need a hero with 20 dex and capable of wearing medium armor to get 3-4 more AC.
You could also argue the Armor of Agility you can buy from the armorer in Baldur's Gate is better than Adamantine Splint on a high dex character, although that depends on whether you value AC or damage reduction more.
Naa, Adamantine is definitely not the best armors in the game. Not even close with your reasoning.
There's also multiple helmets with Crit immunity on them.
Helldusk Helmet -
Infernal Sight: can see in Magical and ordinary darkness up to 12m, and can't be blinded
MAgical Durability: +2 bonus to Saving Throws against spells
Crit immunity
Immolating Gaze Class action
Helm of Balduran -
Helmet heals you for 2 HP at the beginning of every turn
+1 bonus to AC and Saving throws
Stun immunity and Crit immunity.
Best Heavy Armor from Vendor is Armor of Persistence -
20 AC
Magical Plate: all damage reduced by 2
Legendary Persistence: You gain Blade Ward and Resistance (permanent)