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Fermentation can change the flavor profile of your booze, while you are usually aiming for a quite high ethanol, you don't want it to destroy your flavor profile. Also don't expect to hit the ethanol levels on level 1, it get's quite easy the moment you get the add ethonal button. For destillation - every bottle has a flavor profile again. Removing a low % one, will increase your ethanol levels, but also change the flavor profile - it'll also decrease the amount of liquor that you get.
So for starters, just go with lower quality products in the first level, it'll be chill the moment you can add extra ethanol in the bottling.
Depending on which you pick you get different flavours from your mash. You can see those in the graph on the bottom. Every coloured dot is the point where you add one those flavours. If you change how long it'll be fermented you can omit those.
Generally speaking the longer you ferment the more ethanol you'll get, but if you go for a sweet and sour alcohol, but your yeast adds bitter notes, you'll get points subtracted in your score.