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As for why its expensive... https://www.d20pfsrd.com/equipment/special-materials/#TOC-Iron-Cold
Really its one of those "just because" things. Likely its so much because there isn't really a downside, as opposed to say, a silvered weapon.
And not to be too elitist, but wait till you see the pricetag on +3 weapons.
A 2gp dagger costing 4gp to be cold iron is a pittance. And its absolutely worth having as backup just in case.
"This iron, mined deep underground and known for its effectiveness against demons and fey creatures, is forged at a lower temperature to preserve its delicate properties."
It's a rare metal that's hard to work with essentially.