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Although, this is the location I use;
Open the folder My documents / My Games / Fallout3
* Edit the file FALLOUT.ini.
* Inside FALLOUT.ini look for a group called [general].
* Inside the general group, after all the configuration parameters, just copy and paste the following 2 lines:
Now close and save the Fallout 3 configuration file.
This worked for me previously on 32bit XP and now on 64bit Windows 7.